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As for the wrinkles and age spots you already have, all is not lost

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Cigarette Smoke Contains Carbon Monoxide

The process of 'browning' is when white adipose tissue develops characteristics of brown adipose tissue, like increasing the number of mitochondria in the cells (these organelles are the 'power house' of cells, turning the chemical potential of fat stores into energy) and an increase of a protein called UCP1 (uncoupling protein 1) which allows fat to be used to produce heat instead of storing it for long term

As your loved ones will need to be patient, tell them that this behaviour is caused by a lack of nicotine and is only temporary and that it should improve in a few weeks at most