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In the case of acrolein and formaldehyde, the amount formed at the highest voltage of 4.8V was an order of magnitude higher than the amount at the lowest voltage of 3.3V

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From Ghosh et al

The researchers used gas and liquid chromatography to determine what was in the vapor, looking at the first puffs as well as later puffs after the device heated up and reached a steady state. Not all puffs are equal One finding was that the first and last puffs produce widely varying emissions