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doi: 10.1016/j.freeradbiomed.2007.12.029

Molecular modelling analyses show that the high toxicity of NAPQI can be explained in terms of its higher kinetic lability, lower solubility in water and possibly lower thermodynamic stability.

Thus, while there are human data supporting biological activity for garlic preparations, direct evidence for intact allicin systemic exposure is weak and must be interpreted cautiously (Nakamoto et al., 2025